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张国防
  • 职  称:教授(博士生导师)
  • 毕业学校:德国慕尼黑工业大学(博士)  德国弗莱堡大学(博士后)
  • 电  话:029-81530830
  • 电子邮箱:gfzhang@snnu.edu.cn
  • 研究方向:金属有机化学

个人简介


  主要从事有机金属化学和含能材料化学方面的研究和教学工作。教学上,主要讲授《配位化学》、《金属有机化学》、《化工基础与实验》和《高等无机化学》等课程。科研上,先后主持国家自然科学基金面上项目1项, 科技部863项目子项目2项,西安近代化学研究所横向项目多项 。在国内外学术刊物上发表论文70余篇,其中SCI源期刊论文60余篇,申请国家发明专利40余项,授权发明专利30项。目前主要从事固体推进剂用燃速催化剂、化学安定剂等的设计和合成工作。


代表性成果

1. A. Qasem, X. Zhang, Z. Y. Xie, Q. S. Zhang, H. M. Sun, Z. W. Gao, J. Yang, H. Khan, W. Q. Zhang,* B. Hu,* and G. F. Zhang*, Triazine-augmented catalytic activity of cyclobutadiene tricarbonyl Fe(0) complexes for thermal decomposition of

ammonium perchlorate[J]. Organometallics, 2023, 42, 384-391.

2. R. Z. Xu, L. F. Yang, H. C. Fang, Z. Y. Mi, Y. P. Lv, L. P. Jiang, X. L. Fu, J. Z. Li, and G. F. Zhang*, Copper complexes in carbon nanotubes as catalysts for thermal decomposition of energetic oxidizers [J]. ACS Appl. Nano Mater., 2022, 5, 14942-14953.

3. L. F. Yang, R. Z. Xu, Z. Y. Mi, Y. T. Wan, X. L. Fu, L. P. Jiang, Y. J. Jian*, J. Z. Li*, and G. F. Zhang*, Enhanced anti-migration performance of carbon nanotubes confined ferrocenyl compounds and their synergistic catalytic activity on the thermal decomposition of ammonium perchlorate[J]. Mater. Today Chem., 2022, 26, 101168.

4. H. C. Fang, R. Z. Xu, L. F. Yang, Z. Y. Mi, Q. He, H. F. Shi, L. P. Jiang, X. L. Fu and G. F. Zhang*, Facile fabrication of carbon nanotubes-encapsulated cobalt (nickel) salt nanocomposites and their highly efficient catalysis in the thermal degradation of ammonium perchlorate and hexogen[J]. J.  Alloys Compd., 2022, 928, 167134.

5. X. L. Shi, L. F. Yang, L. P. Jiang, F. Q. Bi, G. F. Zhang*, Anti-migration of nitrogen-rich N-heterocyclic ferrocenes and their combustion catalytic properties in the thermal decomposition of energetic oxidizers[J]. Z. Anorg. Allg. Chem. 2022, 648, e202100324.

6. X. L. Shi, W. Q. Cheng, L. P. Jiang, F. Q. Bi, J. Z. Li, G. F. Zhang*, Anti-migration and combustion catalytic performances of ferrocenyl compounds of anilines and alkylamines synthesized by click reaction[J]. Z. Anorg. Allg. Chem. 2021, 647, 463-470.

7. W. Q. Cheng, X. L. Shi, Y. Zhang, Y. J. Jian, G. F. Zhang*, Novel ferrocene-based 1,2,3-triazolyl compounds: Synthesis, anti-migration properties and catalytic effects on oxidizers during combustion[J]. Inorg. Chim. Acta, 2020, 502, 119374.

8. J. Z. Li, C. Y. Wang, X. N. Gao, F. Q. Zhao, K. Zhao, X. Z. Fan, X. Y. Li, G. F. Zhang*, W. Q. Zhang, Z. W. Gao. Alkaline and alkaline earth salts of 5-ferrocenyl-1H-tetrazole. Synthesis, characterization and catalytic effects on thermal decomposition of energetic compounds [J]. Polyhedron 2016, 106, 58-64;

9. C. Y. Wang, J. Z. Li, X. Z. Fan, F. Q. Zhao, W. Q. Zhang, G. F. Zhang*, Z. W. Gao. Ferrocenyl-1H-tetrazole derived transition metal complexes. Synthesis, crystal structures and catalytic effects on thermal decomposition of main components of solid propellants [J]. Eur. J. Inorg. Chem, 2015, 1012-1021;

10. X. L. Liu, W. Q. Zhang, G. F. Zhang*, Z. W. Gao*. Low migratory ionic ferrocene based burning rate catalysts with high combustion catalytic efficiency [J]. New J. Chem. 2015, 39, 155-162;

11. X. L. Liu, W. Q. Zhang, G. F. Zhang*, Z. W. Gao. Ferrocene based ionic burning rate catalysts with polycyano anions: Synthesis, structural characterization, migration and their catalytic effects during combustion [J]. Eur. J. Inorg. Chem, 2015, 1496-1504 (封面文章).



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